ETS Major Field Test Chemistry Practice Test

The first ionization energy refers specifically to the energy required to remove the outermost electron from a neutral atom in the gas phase. This concept is crucial in understanding how elements behave in chemical reactions and how they form ions.

When an atom is in its gaseous state, it is considered isolated, and the outermost electron experiences the effective nuclear charge exerted by the protons in the nucleus. The first ionization energy is a measure of how strongly this outer electron is bound to the atom. Generally, this energy increases across a period on the periodic table due to an increase in nuclear charge without a significant increase in shielding effect, making it more challenging to remove an electron. Conversely, it decreases down a group as the added electron shells increase the distance between the nucleus and the outermost electron, leading to a reduced effective nuclear charge experienced by that electron.

This definition aligns perfectly with the correct answer, distinguishing it from the other options, which refer to different concepts entirely, such as electron affinity or the energies associated with breaking bonds and electron stability.

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